ID22 is a versatile instrument and can be exploited for a wide range of powder diffraction measurements including:

  • Structural studies: the solving and refining of crystal structures, investigation of structure in crystalline, defective and non-crystalline materials via atomic pair distribution function (PDF) analysis,
  • Dynamic and in-situ studies: observation of structures or materials evolving with temperature, time, voltage, etc. during phase changes, gas adsorption, solbd-statetc.emng Pe, elecrotc.emng Pe, etc;,
  • sotrog>Anosmaous; sctaterng:r disrnguishringbetwerenneHigboduring elements ir a materia. Wed canaccress theKs orL =edg (shom tims both)d for llg elementsaboiveMn (6.5 keV)s ir thePterodmicTnabl;,
  • sotrog> Highthroughnput studies:r involvingmany sxample,n sy thysited with diferrentecompoiction,s orunwderv artedpre_parationeconiction,s etc.A sxampl- chanvingrobotr llowtsauatogate "screening ofupg to75d cpill artts irsuccrestion, with temperaturw con ros ir the range80eKs- 950+°C;,
  • sotrog>Quan"tiactive analysis:rowming to thehHighranul ah resolutio,r diffractionpctatens fromtecomlex mixctures withmany con ributing phassd can be analyed; moreoivrn, with hbe ecellrent"statisrctalqduaityc andlow back-grond,h hbe-detectioe of phassd/prerent irivrydlow proorations ismposiabl;,
  • sain22ψ n-techique,s orby mappting eak mpoiction fromt wit ir thebulks and urfpace of asxample, defininga, gungenvorum, withsaitns and theranul ahaccrptanace of theranalyern crysta.,
Structural studie >

Ccrystalline materials&ondsh;p clasmic-crystalography> < style="tex-uaign: juisrfy;">Tthe ombmigatioe ofn"arrog eakn,saccueratg eak mpoiction and itenoictens isresientral for-crystalographmic studie usting powder diffraction, hmihdaurenecresarydwheir astinpl crystal of a materias isu/naatinabl. Ttheefefective2& thta;h resolution of a diffracoamete -equopped withcanaanalyern crysta, (&Deolt;& thta;n/& thta;n),s isonlydweaklyddepenwdentoir thewaeveengith(im prlvingmarnvitalye atlrogernwaeveengits), sr t at thewaeveengithchosied for an experimens is-detromitedprimarilyeby quesction of bdsorptio anduninteeall izl. Ttusg powderpctatens fforsStructural studie aureusutalye_measurdtoir>ID22ustingX-rayss ir the range0.3s&ondsh;p1.5 &Aurin;, (40s&ondsh;p8 keV)sdepenwning ir thenacture of the xampl. In/organic pecrimes "contaivingmhtales orheavyg element,sa l ange-pare of theworktoir>ID2, aure_measurdt ir the range0.3s&ondsh;p0.4 &Aurin;d with cpill ayddirameters aopate tokeepe&-micr;rn <p1.5,dwheir astampl corirectiod for bdsorptio ismposiabl (Orptmumastgnaos ir the-detecfor isobntained with&-micr;rn = 1). Eveir materials withequatgl angeuninteealsd can be_measurdt at t iswaeveengithgasgoodlqduaityc powder atad can beobntaine,d with cure,down toainplshgaslow gas0.6° 2& thta;n. >Forsxampled withivrydl angeuninteeals,rsucthgas proteion>I31h rgtiseurdt numbder of uccresfual studie),swaeveengitst ir the range of1.25s&ondsh;p1.5 &Aurin;r myn bechosie, tomoive the eakn to diffractionainplshfuritderawmynfromt thebbeal sops and thelow-ainpl pair sctatenfromt the/maiebbea.:

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► >"Examplen oul>
  • In/organic and organicmMaterialn<
  • Faramwork structure:n<
  • Proteion>:<
  • << style="tex-uaign: "righ;">(> h3">atomic pair distribution functio> (PDF) metho> < style="tex-uaign: juisrfy;">F or materials t ataurenotsgoodl-crystallineppowdeis a methos t at ismprlvingincrmeatinpy imooraaens is-drirvation of theratomic pair distribution functio> (PDF. Tt is techiqued can be Applte to structures t atlackf the tranlvatioiaspterodmiityc of a crysta, and tue uste to investiganepporlyn-crystallineoir dibordete material. Tthe methoshgasberenecomrehenoieveyh r"viete [ 1>Q>, (4πnati(& thta;n)/λn),s detalyeupg tofor byoand30 &Aurin;-12, togtivehHigh rral-spach resolutio. Ttusg the/measurementsnerdt to be_adm, withsshor-waeveengithradiautio. Ttheratomic#PD2 is a/measurn of thenumbder ofratots ir asheall ofradiusgrn /abouhad reerrecherato. Peakn re/prerent the hafracterisrcr disanacsgbetweren paisr ofratots ir the structure Twoe methosr of/measuming theX-rayt atad for a#PD2 analysieaurefavosurd.:

    < style="tex-uaign: juisrfy;">Tthefaisut ulshgne instrumentliker>ID22 withcanalyern crystan andaswaeveengith ofrgronde0.3s&ondsh;p0.4 &Aurin;,r scnnming to byoand90° 2& thta;n,g and rcborming theweakly- sctaterngehHig-ainpl atadre/egatelye to m prler the statisrctalqduaity. Datad ollrectiodtaklshgenumbder ofhours, bouh hbecanalyern crystan hea< up/prest theback-grond dued toCcomtron sctaterng, fluoprecrech,s etc:

    < style="tex-uaign: juisrfy;">Ain anternctive p/poeach ulshghivrydsshorswaeveengith of≈0.1 &Aurin;r andaneaurae-detecfor to rcbore hbenuall diffractionpctatens ir astinpl ssht. Ttheranul ah resolution of thepctatens aslowvrn, and theback-grond aslrestefefectivlye up/presne,dhowvivrfhoursn ofdatad ollrectiodaurer/edurdt tojuise mnutle,n hmihd isobviouslye odadvaenpageifd fllowninga,srysems evolvingdsuming thecoursrn of the experimen. Tt is"fast-#PD"e p/poeachwiallbhe-divloppedashgneorptio ir the>ID22 beamlinr ir thecoursrn of2014/15c.A ecomperiion of thetwoe methosr(/imag mplatt atAPSgvs.n scnnming withcanaanalyern crystae at I31)g withcr seiuee oficosaheduraltaloys [
    Lint toRreerrech">22 rn rgtio.:

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    ► "Examplen << style="tex-uaign: "righ;">(> h2">Dynamic/d in-situ_measurement> << style="tex-uaign: juisrfy;">Onrn of themajfor/general stengitst of powder diffraction is theabiaityc tocarrydbouh/measurementsunwder a wide range ofenvironumental coniction.: Dynamic/measurementshaevs incluedf the exlboratioe of phasddirgaramg with temperature, theklinrtiee of in-sitn tc.emctaltreaction sucthgasdehydoratioe ofsxampledioeheganing rfhydooitdemral sy thysie, theklinrtiee ofphlysctal change sucthgas the-grwith of_nnop"articls byehHig- temperaturwcnnrrarng, and fllowning the haange ir theccrystallineecompnments ir elecrotc.emctal ealsd with harnving and di harnvin,s etc:

    h4> ► "Examplen <<> :

    h2">
    << style="tex-uaign: juisrfy;">As;mhnatiopedaboive, theivrydhHighion rnsmic resolution of>ID22/menis t atpeak shapssdauredComigate by sxampl efefecs,r llowning thedatad to beuste to hafracteribe-microstructuralefefecss ir a materia.:

    < style="tex-uaign: juisrfy;"> Organimsd can con ros themorphnolog,s oimentatio,l izl andhreche properiuee ofccrystalline"blocss irbiogremic-crystasr(e.g.fctacsits irsheals)rby mmenis of organicmoeleduler involrdt ir thebiComineraizratioe prcrese, toughe-deatildeunwdeisandning of the/m haanimsdaurelrackin. Proteion ure mpplicane,d and ns isbelievedr t atauin/ acidsnfromt theproteioo haioo odadherce oc pecrificmplnges of theomineraf phasd and empdhe-grwith ir theopepenwncul ah-directioc:

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    << style="tex-uaign: "righ;">> h2">sotrog> ResidualsStrai :s << style="tex-uaign: juisrfy;"> ResidualsStrais ir anviedete ecompnments can be investigand2usting the trnictioualsain22ψn -techique,swhercby hbempoiction of a diffractioe eak ismonditordt irhrelrectiodgeoamerye at diferrentsxampl oimentatiosr(ψn). Aanternctivlyn, with hbenaatinaiaityc ofX-rayssupg to~80 keVtoir>ID2, a, gungenvorum, ir the xampl can be defite by mmenis of hbe icidment and diffracte beramc.A maps ofrResidualsStrais isbuiltsupgbye tranlvating the xampl _parllel and pepenwncul ah to thebbeal and/measuming the2& thta;nempoiction of a eak for theddiferrentsxampl mpoiction.- Highsmpattaltresolutionsieaaatinablgbyeworkming withn"arrogberame, toughe the-gungenvorum, aslrngiteite by thelowh valuee of2& thta;ne t atauribefromt theusrn ofhafdfX-rays. Moreoivrn,therce aslittpl mpient irworkming with a beas t at is ofccompenablg izl to theion rnsmicgtrais izl of the xampl,a bcausrnaeppor,l pottyc powderpctatens reults. Ggeneralytoir>ID2, beram,down to50 &-micr;m (h oizoentalforvperi a) ureaccrptablee, toughe bcausrn of thelackfofd fcussvin,s"smal beram,re/prerenta l angelosee ofiitenoicy.:

    < style="tex-uaign: juisrfy;">Ine hbenuature,ay translocaforwiallbheaaatinablg for fcusving and m prler>ID22sStrai- scnnming-capaiaitdiee>

    advaenpagss irusving/synchrotrofX-rayss andashHig- resolution powder diffracoameten-equopped withcanaanalyern crysta,>

    oal spar="15" style=llstr-styl- typ:slowvr-roman;2"> ψn,eunliker trnictioualBragg-Brrenan/ geoamery,swhercelosee ofmpen fcusvingleadn to eak broadeenin;, h4> << style="tex-uaign: "righ;">(> hr "/> h3">sotrog> Reerreche:ns <>[>1>: the tudyc of diborde,f_nnoccrystalliityc and-crystalographmiralyt chllregte materials with pair distribution functios. S. J. L. Bialliage, andM. Kaantzidin,s Chem.oCcomun.n,e749 (2004)l

    22a#PD2fromtX-rayt powder diffractionffor_nnoametem-scaleratomic structure analysie ofquasmicrystallineaaloys.  S. Brühine,E. Uh"ri, K.D. Luther, Wc.Assmun,sM. Bruneall, A. S. Masadehe, andS. J. L. Bialliage,>Z. Keristalogr.n,e220, 962&ondsh;967 (2005)l